HEXAMETHYL DISILOXANE

PRODUCT IDENTIFICATION

CAS NO. 107-46-0, 864719-97-1

HEXAMETHYLDISILOXANE

EINECS NO. 203-492-7
FORMULA [(CH3)3Si]2O
MOL WT. 162.38
H.S. CODE 2931.00.9010
TOXICITY Oral Rat LD50: 8ml/kg
SYNONYMS Bis(trimethylsilyl) ether; Bis(trimethylsilyl) oxide;
Hexametildisiloxano (Spanish); Hexaméthyldisiloxane (French); HMDSO; Oxybis(trimethylsilane); Dow corning 200; 1,1,1,3,3,3-Hexamethyldisiloxane; Hexamethyldisiloxane;
SMILES [Si](O[Si](C)(C)C)(C)(C)C

CLASSIFICATION

Siloxane

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

clear liquid

MELTING POINT -68 C
BOILING POINT 100 - 101 C
SPECIFIC GRAVITY 0.76 - 0.77
SOLUBILITY IN WATER

Insoluble

pH  
VAPOR DENSITY  

AUTOIGNITION

340 C

log Pow 4.2 (Octanol-water)
HENRY LAW CONSTANT 0.0453 (atm-m3/mole at 25 C)
OH RATE 1.38E-12 (cm3/molecule-sec at 25 C Atmospheric )

NFPA RATINGS

Health: 1 Flammability: 3 Reactivity: 0

REFRACTIVE INDEX

1.3745 - 1.3750

FLASH POINT

-1 C

STABILITY Stable under ordinary conditions.

GENERAL DESCRIPTION & EXTERNAL LINKS

Wikipedia Linking

Google Scholar Search

Material Safety Data Sheet

http://jcp.aip.org/
The dissociative recombination of electrons with the hexamethyldisiloxane (HMDSO) cation
((CH3)3Si–O–Si(CH3)3)+ and the pentamethyldisiloxane cation ((CH3)3Si–O–Si(CH2)2)+ as well as the ion-molecule reaction between Ar+ and HMDSO have been studied at 300 K using a flowing afterglow Langmuir probe-mass spectrometer apparatus. The rate constants for these reactions, measured directly for the first time, are, respectively, α1 = 1.8×10−6, α2 = 3.6×10−6 cm3/s, and k = 2.0×10−9 cm3/s with uncertainties of ±30%. In addition, the electronic attachment to neutral HMDSO was also studied and an upper limit value of the rate constant was determined to be β = 3.3×10−11 cm3/s

Local
Siloxane is a silica-based organic or inorganic polymer with base structure R
2SiO in which R is alkyl group. Siloxane polymer exists in a form of oily liquid, grease, rubber, resin, or plastic. Hexamethyldisiloxane is a general purpose volatile siloxane fluid having properties of clear; non-toxic; low surface tension and non-greasy as well as high compatibility with the lipophilic; high compressibility; high damping action; high dielectric strength; high water repellency and high stability. Unlike other volatile carriers, volatile silicone fluids do not cool the skin when they evaporate. Applications include personal care products; chemical manufacturing; plastic additives; damping fluid; water repellant; hydraulic fluid; lubricants; heat transfer fluid; mold release agent; break fluids; corrosion inhibition film; polish component;

SALES SPECIFICATION

APPEARANCE

Clear liquid

ASSAY

99.0% min

VISCOSITY

0.65 (mm2.s-1 at 25 C)

SILANOL 1.0 max
TRANSPORTATION
PACKING 160kgs in drum
HAZARD CLASS 3 (Packing Group: II)
UN NO. 1993
OTHER INFORMATION
Hazard Symbols: F, Risk Phrases: 11, Safety Phrases: 16